1. Panimula
A217 cast steels WC6 and WC9 (industry shorthand for the 1¼Cr–½Mo and 2¼Cr–1Mo cast grades, ayon sa pagkakabanggit) are purpose-designed low-alloy Cr–Mo steels for pressure-retaining components in elevated-temperature service.
WC6 is typically specified where good toughness and moderate creep strength are required up to roughly ~520–540 °C;
WC9 provides higher long-term strength and oxidation resistance and is used where service temperatures and creep demand approach ~550–580 °C.
Successful use of these materials depends as much on foundry practice, heat treatment and welding discipline as on the nominal chemistry—poor processing is the root cause of most field failures.
This review compares WC6 vs WC9 from metallurgy and properties through fabrication, service use, competing alternatives, and practical procurement guidance.
2. What are A217 Alloy Cast Steels WC6 and WC9?
ASTM A217 Standard Context
ASTM A217 / ASME SA217 is the globally recognized specification governing martensitic and austenitic alloy cast steels
ginagamit sa pressure-retaining components—valves, mga flanges, mga angkop na bagay, headers, and reactors—exposed to high-temperature service (≥343 °C / 650 °F).
- Historical Note: First issued in 1937, the standard has undergone continuous refinement, with the 2024 revision updating composition tolerances, heat treatment requirements,
and mechanical property ranges to align with modern energy infrastructure, kasama na ang ultra-supercritical power generation and advanced petrochemical reactors. - Within the standard, WC6 and WC9 fall under the martensitic Cr–Mo alloy family.
Hindi tulad ng austenitic grades (hal., C12, CN7M) that rely on high nickel (>9 wt%) para sa paglaban sa kaagnasan,
martensitic alloys contain low Ni (<0.5 wt%) and derive their performance primarily from kromo (Cr) at molibdenum (Mo) additions.
This fundamental distinction makes WC6/WC9 more suitable for mataas na load, creep-limited environments, where austenitics—though more corrosion resistant—would soften or lose strength.
3. Chemical Composition of A217 WC6 vs WC9
Ang performance distinction between WC6 and WC9 alloys lies primarily in their komposisyon ng kemikal, which governs microstructure evolution, paglaban sa creep, oxidation behavior, at weldability.
Nominal Composition Ranges (ASTM A217)
Elemento | WC6 (1.25Cr–0.5Mo) (wt%) | WC9 (2.25Cr–1Mo) (wt%) | Function in Alloy |
Carbon (C) | 0.15 – 0.30 | 0.15 – 0.30 | Provides martensitic hardenability and forms carbides for strength; excessive carbon risks brittleness. |
Mga mangganeso (Mn) | 0.50 – 1.00 | 0.50 – 1.00 | Improves hardenability and acts as a deoxidizer; too much reduces creep strength. |
Silicon (Si Si) | 0.50 – 1.00 | 0.50 – 1.00 | Pinahuhusay ang paglaban sa oksihenasyon (SiO₂ film) and strengthens ferrite matrix. |
Chromium (Cr) | 1.00 – 1.50 | 2.00 – 2.50 | Improves oxidation and corrosion resistance; stabilizes carbides (M₇C₃, M₂₃C₆). |
Molibdenum (Mo) | 0.44 – 0.65 | 0.90 – 1.20 | Provides creep resistance; forms Mo₂C carbides to resist grain boundary sliding. |
Nikel (Ni) | ≤ 0.50 | ≤ 0.50 | Residual element; improves toughness but limited to prevent retained austenite. |
Sulfur (S) | ≤ 0.030 | ≤ 0.030 | Controlled impurity; excess causes hot cracking during casting/welding. |
Posporus (P) | ≤ 0.030 | ≤ 0.030 | Controlled impurity; excess leads to temper embrittlement in service. |
Bakal na Bakal (Fe) | Balanse | Balanse | Forms the ferritic/martensitic matrix. |
4. Mga Katangian ng Mekanikal & Elevated-Temperature Behavior of A217 WC6 vs WC9
Room-Temperature Mechanical Properties
Both WC6 and WC9 alloys are designed to provide high strength and toughness at ambient and moderate service conditions.
The values below are from ASTM A217 requirements and industrial practice after standard heat treatment.
Pag-aari | WC6 (1.25Cr–0.5Mo) | WC9 (2.25Cr–1Mo) | Remarks |
Lakas ng Paghatak (MPa) | 485 – 655 | 585 – 760 | WC9 has higher Cr & Mo → stronger carbide strengthening. |
Yield Lakas (0.2% Offset, MPa) | ≥ 275 | ≥ 380 | Higher Cr/Mo in WC9 increases yield resistance. |
Pagpapahaba (%) | 18 – 22 | 17 – 20 | WC6 slightly more ductile; WC9 slightly stronger but less ductile. |
Ang katigasan ng ulo (HB) | 150 – 190 | 170 – 220 | WC9 tends to be harder, reflecting higher carbide density. |
Charpy V-Notch Impact Energy (J, RT) | 40 – 60 | 35 – 50 | WC6 retains slightly better toughness at room temperature. |
Elevated-Temperature Strength & Paglaban sa Creep
In high-temperature service, creep rupture properties are the critical design parameter for pressure-retaining components such as valves, headers, and piping.
Pag-aari | WC6 (1.25Cr–0.5Mo) | WC9 (2.25Cr–1Mo) | Remarks |
Max Continuous Service Temp (°C) | ~538 °C (1,000 °F) | ~595 °C (1,100 °F) | WC9 tolerates higher temperatures due to 2.25% Cr + 1% Mo. |
100,000 h Creep Rupture Strength @ 538 °C | ~85 MPa | ~120 MPa | WC9 exhibits ~40% higher creep rupture resistance. |
100,000 h Creep Rupture Strength @ 595 °C | Hindi inirerekumenda (rupture <50 MPa) | ~75 MPa | WC9 is suitable up to 595 °C; WC6 loses strength. |
Paglaban sa oksihenasyon | Katamtaman | Mataas na | Cr content (2.25% in WC9) forms more protective Cr₂O₃ film. |
5. Processing Technology of A217 WC6 vs WC9
The successful manufacture and deployment of ASTM A217 Grade WC6 and WC9 alloy cast steels depends on precisely controlled processing technology.
Because these alloys are used in critical, mataas na temperatura, pressure-retaining components tulad ng mga balbula, headers, mga casings ng turbina, and reactor housings, even small deviations in processing can lead to premature failure.
Welding: Preventing brittle martensite and cracking
- Preheat: Thick sections require preheat (commonly 180-250 ° C) to slow cooling and reduce hydrogen-induced and martensite formation.
Exact preheat depends on thickness, section restraint, and welding procedure qualification. - Mga Consumable: Use low-hydrogen electrodes / filler metals specifically qualified for Cr–Mo service and creep applications.
Select fillers compatible with base metal chemistry and required post-weld properties. - Interpass temperature control: Maintain within qualified limits to avoid local hardening.
- PWHT (Post Weld Heat Treatment): Mandatory in most high-temperature service cases.
PWHT restores temper to HAZ and reduces residual stress—common practice is tempering/soaking in the 600-700 ° C saklaw (procedure must be qualified;
time at temperature depends on section thickness). Field PWHT must be executed per a qualified WPS/PQR. - Avoiding brittle martensite: Rapid cooling can form untempered martensite in HAZ—hence preheat and PWHT are indispensable.
Machining: Overcoming hardness and workability
- Structure after HT: Tempered martensite/bainite has relatively high strength; use appropriate carbide tooling, low cutting speeds and flood coolant.
- Distortion control: Machining should account for possible distortion when removing restraint—stress-relief heat treatment sequencing and finishing passes minimize warpage.
- Surface integrity: Avoid surface grinding temperatures that can re-harden surfaces.
Casting Considerations
WC6 and WC9 are often manufactured as large sand-cast components (Mga balbula, steam chests, turbine casings up to 10 tonelada).
Paghahagis requires meticulous process control to avoid metallurgical defects.
- Melting practice: For critical castings, use VIM/VAR or argon-shielded melting to control impurities and inclusion content. Clean melts reduce fatigue and creep initiation sites.
- Gating and risering: Design for directional solidification, adequate feeding and chills to eliminate shrinkage porosity.
Castings for pressure service often require radiographic acceptance levels. - Heat treatment after casting: Normalize/anneal cycles relieve stresses and refine microstructure prior to tempering.
Final tempering produces the desired balance of strength/toughness. - NDT: Radiography, ultrasonic testing and acceptance criteria per code required for pressure components.
6. Paggamot ng Heat & Surface Treatment of A217 WC6 vs WC9
Paggamot ng Heat
The performance of ASTM A217 WC6 (1.25Cr–0.5Mo) and WC9 (2.25Cr–1Mo) alloys is critically dependent on heat treatment, which governs their microstructure, mekanikal na mga katangian, and high-temperature service life.
Hakbang | WC6 (1.25Cr–0.5Mo) | WC9 (2.25Cr–1Mo) | Layunin |
Awteritisismo | 900–955 °C (1,650–1,750 °F), hold 2–4 h | 930–980 °C (1,710–1,800 °F), hold 2–4 h | Matunaw ang mga karbid, homogenize chemistry, refine grains |
Pagpapawi | Air cool or oil spray for thick sections | Air cool (smaller castings), oil/polymer for heavy sections | Avoid retained austenite, minimize cracking |
Paghina ng loob | 660–705 °C (1,220–1,300 °F), 2 Mga siklo | 675–740 °C (1,245–1,360 °F), 2 Mga siklo | Precipitate secondary carbides, improve creep resistance, Bawasan ang brittleness |
PWHT (hinang) | 621–677 °C (1,150–1,250 °F) | 650–705 °C (1,200–1,300 °F) | Relieve stresses, temper HAZ martensite |
Paggamot sa ibabaw
Although WC6 and WC9 provide inherent oxidation and creep resistance, Inhinyeriya sa ibabaw can extend component life in corrosive or erosive environments.
Paggamot | Paraan | Benepisyo | Typical Application |
Pagsabog ng Shot / Grit Pagsabog | High-velocity abrasive particles | Removes oxide scale, improves surface cleanliness, enhances fatigue life | Post-heat treatment cleaning |
Nitriding | Gas or plasma nitriding (500–550 °C) | Improves surface hardness (hanggang sa 900 HV), Paglaban sa Pagsusuot | Mga upuan ng balbula, moving parts in turbines |
Aluminizing | Pack cementation or vapor deposition | Forms protective Al₂O₃ layer, increases oxidation resistance >600 °C | Power plant superheaters, petrochemical reactors |
Chromium-Rich Overlay Welding | Hardfacing with high-Cr electrodes or strip cladding | Enhances hot corrosion and erosion resistance | Boiler valves, refinery equipment |
Diffusion Coatings (Al, Si Si, Cr) | High-temperature diffusion process | Improves hot corrosion and carburization resistance | Furnace components |
Thermal Spray Coatings (HVOF, Plasma) | WC-Co, Cr₃C₂-NiCr cermet coatings | Resists erosive slurry and steam impingement | Pump impellers, slurry valves |
7. Typical Applications of A217 WC6 vs WC9
A217 WC6 and WC9 alloys are martensitic Cr-Mo low-alloy steels engineered for mataas na temperatura, high-pressure service.
Their combination of tempered martensite microstructure, lakas ng gumagapang, at thermal katatagan makes them indispensable in pagbuo ng kapangyarihan, petrochemical, and process industries.
Power Generation Industry
WC6 (1.25Cr–0.5Mo):
- Subcritical steam service (≤538 °C)
- Mga Bahagi:
-
- Boiler headers and elbows
- Superheater and reheater elements
- Turbine casing sections for intermediate pressures
WC9 (2.25Cr–1Mo):
- Supercritical and ultra-supercritical steam (538–595 °C)
- Mga Bahagi:
-
- High-pressure superheater and reheater headers
- Steam chest valves
- Turbine inlet casings
Petrochemical and Refinery Equipment
- WC6:
-
- Furnace components (tube sheets, combustion chambers)
- Intermediate-temperature heaters (≤538 °C)
- WC9:
-
- Reactor and heater tubes operating up to 595 °C
- Catalyst bed support structures
- High-pressure petrochemical valves
Steam and Heat Transfer Equipment
- Headers and Manifolds: Both WC6 and WC9 are widely used in steam headers where temperature and pressure fluctuate cyclically.
- Heat Exchanger Components: Tube sheets, baffles, and end plates require paglaban sa creep at thermal fatigue tolerance, making these alloys ideal.
- Boiler Valves and Fittings: Swing, gate, globe, and check valves use WC6 or WC9 depending on operating temperature.
Iba pang mga Pang industriya na Aplikasyon
- Mga Daluyan ng Presyon: Small to medium vessels for subcritical/critical steam in industrial power generation.
- Pump Casings and Turbine Components: High-pressure pumps in petrochemical and nuclear applications.
- Furnace and Kiln Components: Supports and internal structures exposed to elevated temperatures for extended durations.
Comparative Service Envelope
haluang metal | Max Continuous Service Temp | Typical Pressure | Typical Components | Recommended Surface Treatment |
WC6 | 538 °C (1,000 °F) | 30 MPa (4,350 psi) | Subcritical boiler headers, Mga balbula, turbine casing sections | Nitriding, aluminizing, pagsabog ng baril |
WC9 | 595 °C (1,100 °F) | 30 MPa (4,350 psi) | Supercritical boiler/reheater headers, Mga balbula, high-pressure turbines | Overlay welding, aluminizing, pagsabog ng baril |
8. Advantages and Limitations of A217 WC6 vs WC9
Ang pag unawa sa mga Mga pakinabang at limitasyon of WC6 and WC9 is critical for mga inhinyero at taga disenyo selecting materials for mataas na temperatura, high-pressure industrial components.
Mga kalamangan
Tampok | WC6 (1.25Cr–0.5Mo) | WC9 (2.25Cr–1Mo) | Mga Tala |
High-temperature strength | Excellent up to 538 °C | Superior up to 595 °C | WC9 is preferred for supercritical steam |
Tempered martensite microstructure | Magandang tigas, ductility | Slightly higher strength, slightly lower ductility than WC6 | Ensures reliability under pressure and thermal cycling |
Paglaban sa gumagapang | Suitable for subcritical service | Optimized for long-term supercritical applications | WC9 exhibits 10–15% higher creep rupture life at elevated temperatures |
Cost-effectiveness | Lower alloy content → reduced cost | Higher alloy content → increased material cost | Budget-sensitive applications may favor WC6 |
Fabrication flexibility | Easier welding and machining due to lower Cr/Mo | Higher hardness and Cr content → requires more careful welding and machining | Preheat and PWHT required for both, but WC9 is more demanding |
Corrosion/oxidation resistance | Adequate for moderate steam and chemical environments | Improved due to higher Cr content | Surface treatments further enhance performance |
Mga Limitasyon
Limitasyon | WC6 | WC9 | Pagbawas / Mga Tala |
Maximum service temperature | Limitado sa 538 °C | 595 °C max | Exceeding limits accelerates creep and may lead to deformation |
Weldability | Katamtaman; preheat and PWHT required | More sensitive; higher hardness and Cr require stricter welding control | Use low-hydrogen consumables, maintain interpass temperature |
Machinability | Good for heat-treated condition | Slightly lower due to higher hardness | Use carbide/CBN tooling and optimized cutting parameters |
Pag crack ng kaagnasan ng stress (SCC) | Susceptible in H₂S or chloride-rich environments | Similar susceptibility, slightly higher Cr offers marginal improvement | Avoid service with H₂S >50 ppm or Cl⁻ >100 ppm |
Gastos | Economical | More expensive due to higher alloy content | Use WC6 when high-temperature creep is not critical |
9. Comparison with Competing Materials
When selecting mataas na temperatura, pressure-retaining materials, engineers often evaluate WC6 and WC9 against alternative alloy steels and stainless steels.
Key Competing Materials
- Carbon Steel (CS): Low-alloy, matipid sa ekonomiya, suitable for low-to-moderate temperatures (<400 °C), but poor creep and corrosion resistance.
- Chromium-Molybdenum Steel Plates (hal., ASTM A335 P11/P22): Forged or welded pressure pipe material, higher creep resistance than CS, less expensive than WC9 castings.
- Austenitic hindi kinakalawang na asero (304, 316, 321, 347): Napakahusay na paglaban sa kaagnasan, suitable for moderate temperatures (≤650 °C), lower strength and creep resistance compared with WC9.
- Mga haluang metal ng Nickel (Inconel 600/625, Bilisan mo na): Outstanding corrosion and high-temperature strength (up to 700–1,000 °C), but very expensive and difficult to fabricate.
- Other Low-Alloy Cast Steels (hal., ASTM A217 Grade C12, CN7M): Austenitic cast steels, good corrosion resistance but lower strength for high-pressure service.
Comparative Performance Table
Pag-aari / Tampok | WC6 (1.25Cr–0.5Mo) | WC9 (2.25Cr–1Mo) | Carbon Steel | Cr-Mo Steel (P22) | Austenitic Stainless (316/321) | Mga haluang metal ng Nickel (Inconel 625) |
Max Service Temp (°C) | 538 | 595 | 400 | 565 | 600 | 980 |
Creep Strength | Katamtaman | Mataas na | Mababa ang | Katamtaman | Mababa ang | Napakataas na |
Lakas ng Paghatak (MPa) | 500–600 | 550–650 | 400–500 | 500–600 | 500–600 | 700–900 |
Charpy Impact @ 20°C (J) | >40 | >40 | 30–50 | 40–50 | 40–80 | 50–100 |
Paglaban sa oksihenasyon | Katamtaman | Mabuti na lang | Mga Maralita | Katamtaman | Mabuti na lang | Napakahusay |
Paglaban sa kaagnasan | Katamtaman | Mabuti na lang | Mga Maralita | Katamtaman | Napakahusay | Napakahusay |
Weldability | Katamtaman | Katamtaman (requires strict preheat/PWHT) | Napakahusay | Mabuti na lang | Napakahusay | Mahirap |
Gastos | Katamtaman | Mataas na | Mababa ang | Katamtaman | Mataas na | Napakataas na |
Fabrication Complexity | Katamtaman | Mataas na | Mababa ang | Katamtaman | Katamtaman | Napakataas na |
Mga Karaniwang Aplikasyon | Mga Boiler, Mga balbula, subcritical/supercritical headers | Supercritical/reheater headers, mga casings ng turbina | Low-pressure vessels, Email Address * | Pressure piping, moderate temp headers | Corrosive service, moderate temp | Extreme high-temp reactors, pagproseso ng kemikal |
10. Pangwakas na Salita
A217 WC6 vs WC9 are the workhorses of mid-high-temperature pressure systems, enabling the safe, efficient operation of power plants, mga refinery, and petrochemical facilities worldwide.
Their success stems from:
- Targeted Alloying: Cr and Mo deliver oxidation and creep resistance tailored to 400–595°C service, the most common range for industrial high-temperature pressure applications.
- Proven Heat Treatment: Tempered martensite microstructure balances strength, tigas na tigas, and stability—validated by decades of ASTM/ASME testing and field service.
- Pagiging Epektibo sa Gastos: A middle ground between low-performance carbon steels and high-cost advanced alloys, minimizing LCC while meeting safety standards.
While advanced alloys (hal., P91, mga superalloys na nakabase sa nickel) are displacing WC6/WC9 in ultra-high-temperature (>600°C) mga aplikasyon, WC6/WC9 remain irreplaceable for 400–595°C service—where their performance, kakayahang gumawa, and cost align with industrial needs.
For engineers and procurement teams, success with WC6/WC9 hinges on strict adherence to ASTM/ASME standards for composition, paggamot ng init, and fabrication—ensuring these alloys deliver their full 15–25 year service life.
Mga FAQ
Can WC6 and WC9 be welded together or to carbon steel?
Oo nga, but joints must be engineered: use compatible filler metals, preheat, interpass controls and PWHT.
Dissimilar metal joints require attention to matching thermal expansion, galvanic issues and HAZ metallurgy. Follow qualified WPS/PQR and code requirements.
What PWHT is typical after welding?
Field practice commonly uses tempering PWHT in the 600-700 ° C saklaw.
Exact soak temperature/time depends on thickness and must follow qualified procedure; always consult supplier/code.
How long will a WC9 valve body last at 550 °C?
Service life depends on stress, siklo, environment and casting quality.
WC9 is designed for longer creep life than WC6 at elevated temperatures, but predicting life requires creep-rupture data and design stress; perform fitness-for-service analyses for critical components.
Are WC6/WC9 suitable for corrosive chloride-rich environments?
They are not the best choice for severe chloride corrosion (pitting/SSC). Duplex stainless steels or nickel alloys are preferable where chloride stress corrosion is a concern.
What inspections are essential on delivery?
Require chemical analysis (MTC), tensile and hardness (as specified), radiography/UT for pressure castings, dimensional checks and heat-treatment records. Where applicable, impact testing and PMI are prudent.