1. Uvod
NAS S20910 (commonly marketed as Nitronski 50 ili XM-19) and UNS S21800 (commonly marketed as Nitronski 60 ili Legura 218) are advanced austenitic nehrđajući čelici engineered for demanding service.
Both deliver better performance than conventional 300-series grades, but they are optimized for different priorities:
- S20910 (Nitronski 50) je a otporan na koroziju, nitrogen-strengthened austenitic stainless optimized for high corrosion resistance (including sour service), dobra snaga, Izvrsna žilavost (including cryogenic), i dobra zavarivost.
It is often specified where resistance to pitting, SCC and low-temperature toughness are required together with reasonable strength. - S21800 (Nitronski 60) is formulated primarily for wear and galling resistance while retaining corrosion resistance typical of austenitics.
It contains high silicon and manganese for tribological performance and is selected where sliding contact, gašenje, and high wear are the dominant failure modes.
This article compares composition, mechanical and corrosion behaviour, izrada, and real-world application trade-offs so you can select the right alloy for a specific component or environment.
2. What Is UNS S20910 (Nitronski 50)
NAS S20910, Općenito poznat kao Nitronski 50 ili XM-19, je a high-performance nitrogen-strengthened austenitic stainless steel.
It is engineered to deliver a combination of Izvrsna otpornost na koroziju, visoka snaga, duktilnost, i žilavost, including at cryogenic temperatures.
These attributes make it well-suited for demanding industrial applications such as chemical processing, morsko okruženje, and sour-service conditions.
Key material designations and specifications uključivati:
- ASTM A276 / A479 (as XM-19)
- UNS S20910
- IZ 1.3964
Primary characteristics of UNS S20910 (Nitronski 50):
- Otpor korozije: Enhanced by increased chromium, molibden, i sadržaj dušika; highly resistant to pitting and crevice corrosion in chloride environments.
- Mehanička čvrstoća: Stronger than conventional 300-series stainless steels, with excellent yield and tensile properties.
- Ductility and toughness: Maintains performance at both elevated and cryogenic temperatures.
- Fabrication and weldability: Can be machined, formiran, and welded with conventional techniques; solution annealing restores ductility after cold working.
- Nitrogen-strengthened: Nitrogen addition increases yield strength and contributes to pitting resistance without compromising austenitic ductility.
- Application suitability: Listed in NACE MR0175 for sour service, suitable for marine hardware, kemijska procesna oprema, komponente pritiska, and structural applications requiring corrosion resistance and mechanical performance.
3. What Is UNS S21800 (Nitronski 60)
NAS S21800, obično nazvani Nitronski 60 ili Legura 218, je a high-performance austenitic stainless steel designed primarily for wear and galling resistance, while maintaining good corrosion performance typical of austenitics.
Its specialized composition makes it ideal for applications where sliding contact, ljepilo, and high surface stress are primary concerns.
Key material designations and specifications include:
- ASTM A276 / A479 (for bars, šipke, and other wrought forms)
- UNS S21800
Primary characteristics of UNS S21800 (Nitronski 60):
- Wear and galling resistance: Elevated manganese and silicon content, combined with a nitrogen-strengthened austenitic matrix, provides superior resistance to gašenje, ljepilo, and surface seizure.
- Otpor korozije: While not as corrosion-resistant as Nitronic 50 in highly aggressive chloride environments, To nudi Dobar opći otpor korozije suitable for moderate chemical and marine exposures.
- Mehanička čvrstoća: Exhibits high strength in both annealed and cold-worked conditions, with excellent surface hardness after work hardening.
- Fabrication and welding: Can be welded and fabricated using standard methods, though its higher silicon and manganese content may require adjustments in welding filler selection and machining parameters.
- Application suitability: Obično se koristi za stabljike ventila, pričvršćivači, osovine pumpe, bearing surfaces, and other components subjected to repeated sliding contact or wear-intensive service.
4. Typical Chemical Compositions and Alloying Differences
A critical factor distinguishing UNS S20910 (Nitronski 50) and UNS S21800 (Nitronski 60) is their alloying strategy, which directly influences corrosion resistance, mehanička čvrstoća, wear behavior, and fabrication characteristics.
While both are nitrogen-strengthened austenitic stainless steels, they are optimized for different service priorities.
Representative Chemical Compositions (WT%) and Performance Role
Element | UNS S20910 (Nitronski 50) | UNS S21800 (Nitronski 60) | Key Role in Performance |
Ugljik (C) | ≤ 0.06 | ≤ 0.10 | Controls strength, limits carbide formation; low C improves corrosion resistance and weldability |
Krom (CR) | 20–23 | 16–18 | Primary contributor to corrosion resistance; higher Cr in S20910 increases PREN |
Nikla (U) | 11–14 | 8–9 | Stabilizator austenita; povećava žilavost i duktilnost; higher Ni in S20910 supports cryogenic performance |
Mangan (MN) | 5–6 | 8–9 | Increases work-hardening and galling resistance; high Mn in S21800 aids wear performance |
Silicij (I) | ≤ 0.5 | 3.5–4.5 | Improves oxidation and wear resistance; higher Si in S21800 supports galling resistance |
Molibden (Mokar) | 1.5–3 | Nije navedeno / trag | Povećava otpornost na koroziju korozije; present in S20910 to resist chlorides |
Dušik (N) | 0.10–0.20 | 0.08–0.18 | Strengthens austenitic matrix; Poboljšava otpornost na koroziju; supports wear resistance in S21800 |
Željezo (FE) | Uravnotežiti | Uravnotežiti | Element matrice; balances alloying; provides basic austenitic structure |
Interpretation: S20910 emphasizes CR + U + Mokar + N (classic austenitic corrosion alloying with nitrogen strengthening and Mo for pitting resistance).
S21800 trades some chromium and nickel for elevated silicon and manganese, which improve hardness, wear and galling resistance.
4. Mechanical Properties and Temperature Behaviour
NAS S20910 (Nitronski 50) and UNS S21800 (Nitronski 60) exhibit distinct mechanical profiles reflecting their alloying strategies.
Ključna mehanička svojstva
Vlasništvo | UNS S20910 (Nitronski 50) | UNS S21800 (Nitronski 60) | Practical Implication |
0.2% Snaga popuštanja (MPA) | 350–420 | 320–380 | S20910 offers higher baseline strength for corrosion-critical applications; S21800 gains strength via work hardening |
Zatečna čvrstoća (MPA) | 650–750 | 600–700 | S20910 provides slightly higher ultimate strength; S21800 maintains adequate tensile strength with wear focus |
Produženje (%) | 30–45 | 25–40 | S20910 maintains excellent ductility; S21800 is slightly less ductile but sufficient for forming/fabrication |
Tvrdoća (Resurs / Hrc) | HRB ~85 typical annealed | HRB ~85, can be higher with work hardening | S21800’s higher Mn/Si allows superior surface hardness after cold work, enhancing galling resistance |
Žilavost utjecaja (J at room temp) | Izvrstan; retains toughness at cryogenic temps (-196° C) | Dobro; slightly lower than S20910 in cryogenic applications | S20910 preferred in low-temperature or highly dynamic loading applications |
Elevated Temperature Performance | Good up to ~600–700°C | Reasonable; high Si improves oxidation resistance at moderate temperatures | S20910 favored for high-temperature corrosion exposure; S21800 for wear-exposed high-temperature components |
Temperature Behaviour
- Cryogenic Performance:
S20910 retains ~90% of impact energy at liquid helium temperatures, making it suitable for LNG storage, cryogenic piping, i zrakoplovne aplikacije.
S21800 retains reasonable toughness but is not optimized for extreme low temperatures. - Performanse povišene temperature:
Both alloys maintain dimensional stability and strength at moderate elevated temperatures.
Nitronic 50’s Mo content provides additional resistance to high-temperature corrosion, while Nitronic 60’s high Si content improves oxidation resistance in sliding-contact applications. - Rad na stvrdnjavanju:
Both alloys are austenitic and work-hardening, meaning mechanical properties, especially hardness and yield strength, can be increased via cold working.
S21800 benefits most due to high Mn and Si, improving wear and galling performance.
5. Corrosion Resistance and Pitting Resistance (Drvo)
Zamjenjivi broj otpora (Drvo) is a useful indicator of resistance to chloride pitting; it’s calculated from Cr, Mo and N content (simplified form: PREN ≈ Cr + 3.3× mo + 16× n).
- Nitronski 50 (S20910) — higher Cr, Mo and N yield PREN values in the low-to-mid 30s (typical engineering figure ≈ ~34).
That places it well above 316L (PREN ≈ 20–25) and makes it suitable for many chloride-bearing environments, including some marine and sour service (it is commonly accepted for NACE MR0175 qualifying in many conditions—verify certificate). - Nitronski 60 (S21800) — because Mo is typically absent and Cr is lower, PREN is donji (typical mid-20s or less depending on exact chemistry).
While S21800 resists general corrosion reasonably well, jest ne chosen primarily for pitting resistance; umjesto toga, it is used where galling and wear are primary concerns.
6. Nositi, galling and tribological performance
- Nitronski 60 (S21800) je konstruiran za galling resistance and sliding wear.
High silicon and manganese, combined with work-hardening capacity, produce a surface that resists adhesive wear and metal-to-metal seizure.
Typical uses include valve stems, mjesta, pričvršćivači, and pump components where repeated sliding contact occurs. - Nitronski 50 (S20910) ponuda Dobra otpornost na habanje, but its primary strengths are corrosion resistance and toughness rather than optimized galling resistance.
It is sometimes used in wear applications where corrosion control is also required, but for extreme galling environments S21800 usually outperforms it.
7. Izrada, welding and heat-treatment considerations
Zavarivost
- Both alloys are zavariv by standard processes (TIG, MI, Slabost).
- S20910 (higher Ni/N) is highly weldable and retains corrosion resistance after welding when proper procedures and filler metals are used.
Low carbon and stabilized practices can minimize sensitization risk. - S21800 requires attention to heat input and filler selection because its high Si and Mn can influence weld metal composition; preheat/post-weld heat treatment practices depend on component size and code requirements.
Forming and machining
- Both are radno otvrd austenitics; S21800’s higher Si/Mn can make cutting more challenging—tooling and speeds need adjustment.
S20910 in solution-annealed condition is generally easier to machine/form.
Toplotna obrada
- These are austentic alloys—strength is primarily from cold working and alloying; full hardening by quench/tempering is not applicable.
Solution annealing can restore ductility and corrosion resistance (typical anneal ~1000–1100 °C followed by rapid cooling).
Hydrogen/sour service
- S20910’s chemistry and listing in some sour-service guidance make it suitable for H₂S environments (verify NACE/ISO certifications).
For sour service weld procedures and hardness limits (HRC thresholds) are normally enforced.
8. Applications of UNS S20910 vs UNS S21800 Austenitic Stainless Steel
The distinct alloying strategies, mehanička svojstva, and corrosion/wear characteristics of UNS S20910 (Nitronski 50) i UNS S21800 (Nitronski 60) define their suitability across different industrial applications.
Applications of UNS S20910 (Nitronski 50)
UNS S20910 is engineered for visoka otpornost na koroziju, Izvrsna žilavost, i dobra zavarivost, making it ideal for environments where both corrosion and mechanical performance su kritični.
Industrija / Sektor | Tipične primjene | Key Performance Requirement |
Morski & Na obali | Seawater fittings, osovine pumpe, pričvršćivači, ventili | Visoka otpornost na klorid, prevention of pitting/crevice corrosion |
Kemijski & Procesna oprema | Izmjenjivači topline, reaktori, cijevi, tenkovi | Resistance to acids, kloridi, and sour service (Izloženost) |
Kriogene primjene | LNG storage and transfer piping, cryogenic valves | Retains toughness at extremely low temperatures (-196° C) |
Aerospace | Fuel lines, cryogenic components | Visoka snaga, otpor korozije, low-temperature ductility |
Energija & Vlast | Boiler components, turbine parts in corrosive environments | Combination of corrosion resistance and mechanical integrity |
Applications of UNS S21800 (Nitronski 60)
UNS S21800 is optimized for galling and wear resistance while maintaining reasonable corrosion performance.
It is ideal for mechanical components subjected to sliding, adhesive contact, or high surface stress.
Industrija / Sektor | Tipične primjene | Key Performance Requirement |
Ventil & Pump Industry | Stabljike ventila, mjesta, osovine pumpe, pričvršćivači | High resistance to galling, klizna nosača, adhesive seizure |
Industrijski strojevi | Ležajevi, čahure, high-wear mating surfaces | Površinska tvrdoća, work-hardening capability, nisko trenje |
Automobilizam & Teška oprema | Pričvršćivači, high-wear components, pokretači | Galling prevention, durability under repeated sliding or contact |
Morske aplikacije | Deck hardware, mechanical joints | Moderate corrosion resistance with high wear/galling protection |
Kemijska obrada | Mixer shafts, agitator blades | Wear-resistant components where moderate corrosion occurs |
Application Guidance
- Choose UNS S20910 when the primary concern is corrosion resistance in aggressive or sour environments, especially when toughness, zavarivost, and low-temperature performance are required.
- Choose UNS S21800 when gašenje, nositi, and sliding contact dominate failure modes, even if corrosion resistance is less critical.
- In complex assemblies, hybrid designs can leverage both alloys—using S20910 for corrosion-critical parts and S21800 for high-wear mating surfaces.
Surface engineering such as premaz, nitriranje, or PVD treatments can further extend service life when combined with these alloys.
9. Direct Comparison Table: UNS S20910 vs UNS S21800
Značajka / Vlasništvo | UNS S20910 (Nitronski 50) | UNS S21800 (Nitronski 60) | Practical Implication |
Primary Focus | Otpor korozije, žilavost | Wear/galling resistance, površinska tvrdoća | Guides selection based on environment and mechanical stress |
Snaga popuštanja (MPA) | 350–420 | 320–380 | S20910 has higher baseline strength; S21800 can achieve higher surface hardness via cold work |
Zatečna čvrstoća (MPA) | 650–750 | 600–700 | S20910 slightly higher; S21800 optimized for wear resistance rather than ultimate strength |
Produženje (%) | 30–45 | 25–40 | S20910 more ductile; S21800 slightly less but adequate for fabrication |
Tvrdoća (Resurs / Hrc) | HRB ~85 typical annealed | HRB ~85, can increase with work hardening | S21800 better for galling and surface wear applications |
Žilavost utjecaja | Izvrstan; retains cryogenic performance | Dobro; lower at cryogenic temperatures | S20910 preferred in low-temperature or dynamic loading environments |
Otpor korozije | Vrlo visok | Umjeren | Guides alloy choice in chemical, morski, or sour-service applications |
Nositi / Galling Resistance | Umjeren | Vrlo visok | S21800 is the preferred option for moving parts, stabljike ventila, i pričvršćivači |
Izrada & Zavarivanje | Izvrstan; solution annealed or strain-hardened | Dobro; requires consideration for welding filler and machining parameters | S20910 easier to fabricate in complex geometries; S21800 may require tooling adjustments |
Maksimalna servisna temperatura | ~900°C | ~750°C | S20910 suitable for higher temperature corrosion exposure; S21800 for wear-exposed moderate temperatures |
Drvo (Zamjenjivi broj otpora) | ~34 | ~23.4 | S20910 provides superior resistance to pitting and crevice corrosion, Pogotovo u |
10. Zaključak
NAS S20910 vs S21800 are complementary alloys within the Nitronic family.
Pick S20910 where corrosion resistance (especially pitting/crevice and sour service) plus toughness and weldability are paramount.
Pick S21800 where galling and wear dominate and corrosion is a secondary concern.
In many real applications the optimum solution is a combination—design the system so each part sees the alloy best suited to its dominant failure mode, or apply surface engineering to extend service life.
Česta pitanja
Are UNS S20910 and S21800 magnetic?
No—both are fully austenitic (or near-fully austenitic) in the annealed state, with magnetic permeability <1.005 (ASTM A342). Cold working may induce weak magnetism, but this is reversible via annealing.
Can I weld S21800 with standard stainless fillers?
Da, but select fillers and procedures to accommodate S21800’s high Si/Mn chemistry—consult welding procedure specifications and filler supplier guidance.
Which alloy resists sulfide stress cracking (SSC)?
S20910 is commonly accepted for many SSC environments and is used in NACE-subject applications; verify specific NACE/ISO certification and hardness limits.
Is Nitronic 60 (S21800) suitable for seawater?
It has reasonable general corrosion resistance in seawater but lacks the pitting resistance of Nitronic 50 or Mo-bearing grades; if seawater pitting is critical, choose S20910 or a higher PREN alloy.
Can either alloy be heat-treated to increase strength?
These austenitic alloys gain strength mainly by hladno djelo i legiranje; conventional quench/temper treatments are not used to significantly increase strength. Solution annealing restores ductility/corrosion resistance.